You can add our ads to the theme (if you want them to be attached to a specific UI element or available on every page) or inside a post.
Adding ads to a Blogspot theme:
Pasting a code to a theme will display the ad on every page of your Blogspot-based website. You can add the code snippet by adding the 'HTML/JavaScript' gadget:
Navigate to Layout from the left-hand menu
Click "Add a gadget", select "HTML/JavaScript" from the list
Paste the code snippet into the "Content" field and click "Save"
If you would like to have a display or a native banner elsewhere (like the page header or sidebar), just drag and drop the gadget.

Adding the ads to a Blogspot post:
Switch to HTML view in the upper left corner
Paste the code snippet from the websites page
You can also use a Direct Link — just insert it anywhere as a regular link.
Blogspot also allows you to edit the theme code directly, however bear in mind that it has some Blogger-specific tags which may not always be compatible with regular HTML. Adding your Adsterra ads via gadgets is more preferrable.